PMR study of J13"C""H coupling constants in polysubstituted methanes

J13"C""H coupling constants in a number of polysubstituted methanes CH"2X"2 and CHX"3 have been analyzed in terms of substituent electronegativity. The latter parameter does not fit additively a correlation previously found for the J13"C""H constants in monosubstituted methanes.Since all substituent... Ausführliche Beschreibung

1. Person: Lunazzi, L.
Weitere Personen: Taddei, F.
Quelle: in Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy Section Vol. 23, No. 4 (1967), p. 841-844
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Format: Online-Artikel
Sprache: English
Veröffentlicht: 1967
Beschreibung: Online-Ressource
Online Zugang: Online
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Anmerkung: Copyright: Copyright (c) 2002 Elsevier Science B.V.
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520 |a J13"C""H coupling constants in a number of polysubstituted methanes CH"2X"2 and CHX"3 have been analyzed in terms of substituent electronegativity. The latter parameter does not fit additively a correlation previously found for the J13"C""H constants in monosubstituted methanes.Since all substituents show a deviation in the same direction from an additivity rule and this deviation is related to the electronegativity of X, a general expression for the J13"C""H of all the polysubstituted methanes considered in terms of substituent electronegativity and CX bond distance is derived. 
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