S'"H type reactions of substituted allylic compounds

S'"H reactions of allyl sulfides and halides with phenyl radicals are reported. Thermal decomposition of phenylazotriphenylmethane with allyl sulfides and bromide has been shown to give allylbenzene. This apparent substitution reaction involves attack of a phenyl radical on the terminal unsaturated ... Ausführliche Beschreibung

1. Person: Migita, T.
Weitere Personen: Kosugi, M.; Takayama, K.; Nakagawa, Y.
Quelle: in Tetrahedron Vol. 29, No. 1 (1973), p. 51-55
Weitere Artikel
Format: Online-Artikel
Sprache: English
Veröffentlicht: 1973
Beschreibung: Online-Ressource
Online Zugang: Online
Volltext
Tags: Hinzufügen
Keine Tags. Fügen Sie den ersten Tag hinzu!
Anmerkung: Copyright: Copyright (c) 2002 Elsevier Science Ltd
LEADER 01889nma a2200349 c 4500
001 NLEJ17581774X
003 DE-601
005 20151014210431.0
007 cr uuu---uuuuu
008 070505s1973 000 0 eng d
016 7 |a 2007072-X  |2 DE-600 
024 8 |a S0040-4020(01)99375-5 
035 |a (DE-599)GBVNLZ17581774X 
040 |b ger  |c GBVCP 
041 0 |a eng 
084 |a sdj  |2 natliz 
245 0 0 |a S'"H type reactions of substituted allylic compounds  |h Elektronische Ressource 
300 |a Online-Ressource 
500 |a Copyright: Copyright (c) 2002 Elsevier Science Ltd 
520 |a S'"H reactions of allyl sulfides and halides with phenyl radicals are reported. Thermal decomposition of phenylazotriphenylmethane with allyl sulfides and bromide has been shown to give allylbenzene. This apparent substitution reaction involves attack of a phenyl radical on the terminal unsaturated carbon atom of the allyl sulfide; the reaction in α,α-dimethylallyl ethyl sulfide produced 2-methyl-4-phenylbutene-2. To estimate the relative reactivities of allylic substrates towards phenyl radicals, competitive reactions of phenyl radicals with allylic compounds and carbon tetrachloride were investigated. The data indicate that the radical formed by addition of a phenyl radical to the allylic sulfide looses thiyl radicals almost quantitatively. 
533 |a Online edition  |f Elsevier Journal Backfiles on ScienceDirect 1907 - 2002 ; 041023-8 
700 1 |a Migita, T. 
700 1 |a Kosugi, M. 
700 1 |a Takayama, K. 
700 1 |a Nakagawa, Y. 
773 0 8 |i in  |t Tetrahedron  |d Amsterdam : Elsevier  |g Vol. 29, No. 1 (1973), p. 51-55  |q 29:1<51-55  |w (DE-601)NLEJ175783357  |x 0040-4020 
856 4 0 |u http://linkinghub.elsevier.com/retrieve/pii/S0040-4020(01)99375-5 
901 |a OLC 
912 |a ZDB-1-SDJ 
912 |a GBV_NL_ARTICLE 
951 |a AR 
952 |d 29  |j 1973  |e 1  |h 51-55 

Ähnliche Einträge

Keine ähnlichen Titel gefunden

Privacy Notice Ask a Librarian New Acquisitions